An advanced signal processing technique for deriving grain size information of bedload transport from impact plate vibration measurements

A reliable characterization of bedload transport is required to gauge the engineering and theoretical issues related to the dynamics of sediments transport in rivers. However, while significant advances have been made in the development of monitoring techniques, robust quantitative predictive relationships have proven difficult to derive. In this article, we develop a dedicated signal processing technique aimed at improving the usage of impact plate measurements for material transport characterization. Our set‐up consists of a piezoelectric hydrophone mounted on the bottom side of a stainless steel plate, thus acting as a ‘sediment vibration sensor’. While the classical analysis with such systems is usually limited to rather simple procedures, such as impact counting, a large amount of useful information is contained in the actual waveform of the impact signal, which conveys the force and the contact time that the bedload imposes on the plate. An advanced signal processing technique called ‘first arrival atomic decomposition’ is used to improve the characterization of bedload transport by analysing the amplitude and frequency attributes of each single impact. This new processing approach proves to be well suited for bedload transport monitoring using plate systems and allows us to establish a relationship between the median grain size (D₅₀) and the impact signal properties. This link is first observed and validated with controlled flume experiments and then applied to continuous impact records in a small gravel‐bed river during a flood event. The estimated D₅₀ offers a novel possibility to observe the time‐varying grain size distribution of bedload transport. Copyright © 2014 John Wiley & Sons, Ltd.     

The influence of fractionation of REE-enriched minerals on the zircon partition coefficients

Zircon is widely used to simulate melt generation, migration and evolution within the crust and mantle.The achievable performance of melt modelling generally depends on the availability of reliable trace element partition coefficients(D).However, a large range of D_(REE)values for zircon from natural samples and experimental studies has been reported, with values spanning up to 3 orders of magnitude.Unfortunately, a gap of knowledge on this variability is evident.In this study we model the crystallization processes of common REE-bearing minerals from granitic melts and show that the measured zircon D_(REE)would be elevated if there is crystallization of REE-enriched minerals subsequent to zircon.Nevertheless, compared to zircon D_(REE)values measured from experimental studies, this mechanism appears to have a less significant influence on those from natural granite samples since the quantity of crystallized REE-enriched minerals is very low in natural magmatic systems and/or most of them crystallize prior to zircon.Combined with recently published studies, this work supports that analysis of natural zircon/host groundmass pairs provides more robust D_(REE)values applicable to natural systems than those measured from experimental studies, which can be used to constrain the provenance of detrital zircons.     

Trace elements and cathodoluminescence of quartz in stockwork veins of Mongolian porphyry-style deposits

The combination of scanning electron microscope–cathodoluminescence (CL), fluid inclusion analysis and high-resolution electron probe microanalysis of Al, Ti, K and Fe in vein quartz has yielded results permitting a greater understanding of the complex mineralisation of the Central Oyu Tolgoi and Zesen Uul porphyry-style deposits, southern Mongolia. These data demonstrate the relationship between quartz precipitation, dissolution and ore deposition as the mineralising fluid chemistry changed through time. Four major quartz generations are identified in the A-type veins from the stockworks of both the Central Oyu Tolgoi (OTi to OTiv) and Zesen Uul deposits (ZUi to ZUiv). Despite differences in the associated alteration and mineralisation style, the observed CL textures and trace element signatures of the quartz generations are comparable between deposits. The OTi and ZUi stage formed both the primary network of A-type veins and pervasive silicification of the host rock. Using the Ti-in-quartz geothermometer, crystallisation temperatures for OTi and ZUi of between 598°C and 880°C are indicated. The main stage of sulphide mineralisation was accompanied by the dissolution of pre-existing quartz (OTi and ZUi) and precipitation of a weakly luminescent generation of quartz (OTii and ZUii) with a low Ti content, reflected in a calculated temperature drop from approximately 700°C to 340°C in Central Oyu Tolgoi and 445°C in Zesen Uul. OTii and ZUii stage quartzes show high and variable Al concentrations. The next stage of quartz in both deposits (OTiii and ZUiii) forms a fine network of veins in cracks formed in pre-existing quartz. OTiii and ZUiii quartz contain measurable fluid inclusions of moderate salinity (3–17.1 wt.% NaCl eq.), entrapped in the temperature range 256°C to 385°C. OTiii and ZUiii are not related to any sulphide mineralisation. The final OTiv and ZUiv stages are characterised by quartz–calcite micro-breccias that penetrate the A-type veins. Based on the calculated entrapment temperatures, the OTiv/ZUiv stage crystallised between 212°C and 335°C, and the quartz is characterised by elevated but variable Al and Fe contents. The CL and trace element signatures of the OTi to OTiii and ZUi to ZUiii stages of the two Mongolian porphyries show similar features to those observed in porphyry-style deposits from other regions. This suggests that a common sequence of quartz crystallisation occurs during the formation of early veins in many porphyry copper systems.     

Characterization of the zircon Ce anomaly for estimation of oxidation state of magmas: a revised Ce/Ce* method

Mineralogy and Petrology - As a proxy of magmatic oxidation state, the accurate characterization of the Ce anomaly of zircon is of great significance since it can give important information for...